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Question

The standard reduction potentials of zinc, cadmium and copper are −0.76 V,−0.4 V and 0.34 V respectively. Select the correct statement.

A
Copper can reduce both Zn2+ and Cd2+ ions.
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B
Cadmium can reduce both Zn2+ and Cu2+ ions.
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C
Zinc can reduce Cu2+ ion but cannot reduce Cd2+ ion.
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D
Zinc can reduce both Cu2+ and Cd2+ ions.
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Solution

The correct option is D Zinc can reduce both Cu2+ and Cd2+ ions.
Given that the standard reduction potentials of zinc, cadmium, and copper are 0.76 V, 0.4 V and 0.34 V respectively.

Hence, the standard reduction potential of zinc < standard reduction potential of copper.

Also, the standard reduction potential of zinc < standard reduction potential of cadmium.
Therefore, both Cu2+ and Cd2+ ions get reduced more easily as compared to Zn2+.
Hence, zinc can reduce both Cu2+ and Cd2+ ions.

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