The correct option is A SO2
Solvay process is extensively used for the industrial preparation of sodium carbonate. The process involves the following reactions:
2NH3+H2O+CO2→(NH4)2CO3
(NH4)2CO3+H2O+CO2→NH4HCO3
NH4HCO3+NaCl→NaHCO3+NH4Cl
2NaHCO3→Na2CO3+H2O+CO2
So, SO2 is not used in solvay process.