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Question

The third line of the Balmer series in the emission spectrum of the hydrogen atom is due to the transition from the :

A
fourth Bohr orbit to the first Bohr orbit
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B
fifth Bohr orbit to the second Bohr orbit
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C
sixth Bohr orbit to the third Bohr orbit
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D
seventh Bohr orbit to the third Bohr orbit.
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Solution

The correct option is A fifth Bohr orbit to the second Bohr orbit
In the atomic emission spectra of the hydrogen atom, the emission lines from an excited state nth Bohr orbit (n>2) to second Bohr orbit (n=2) is called Balmer series. Thus emission from n>2 to n=2 constitutes the various spectral lines of the Balmer series.

For the third line of Balmer series the transition should take place from n=2+3=5 to n=2 Bohr orbit i.e. from fifth Bohr orbit to second Bohr orbit.

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