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Question

The time taken for effusion of 64 mL of oxygen will be same as the time taken for the effusion of which of the following gases under identical conditions?
  1. 100 mL of N2
  2. 64 mL of H2
  3. 64 mL of CO2
  4. 45.24mL of SO2


Solution

The correct option is D 45.24mL of SO2
Rate of diffusion=Volume of gas diffusedtime taken
rO2=64t
rg=Vt
rO2rg=64V

Option (a)
rO2rH2=MH2MO2
64V=232 or V=256 mL

Option (b)
rO2rN2=MN2MO2
64V=2832 or V=68.42 mL 

Option (C)
rO2rCO2=MCO2MO2
64V=4432 or V=54.58 mL

Option (d)
rO2rSO2=MSO2MO2
64V=6432 or V=642=45.25 mL
Hence, the correct answer is option (d).

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