The toxic compound 2,4−dinitrophenol has Ka=10−4M. In an experiment, a buffer solution of 2,4−dinitrophenol was prepared with the pH adjusted to 5. Calculate the ratio of the concentrations of the dissociated ion to the undissociated acid:
A
0.01
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B
0.1
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C
10
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D
100
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Solution
The correct option is C10 pH=pKa+logsaltacid
pKa=−log(10−4)=4
Substituting,
logsaltacid=pH−pKa=5−4=1
So, Saltacid=10
Ratio of the concentrations of the dissociated ion to the undissociated acid =10