Vapour desity concept
Weight of a unit volume of gas or vapor compared to (divided by)
the weight of an equal volume of air (or, sometimes, hydrogen)
vapour density = mass of n molecules of gas / mass of n molecules of hydrogen
vapour density = molar mass of gas / molar mass of H2
vapour density = molar mass of gas / 2.01
Vapour density of gas = molar mass /2.01
Molar mass of gas mixture = 38.3*2.01= 77
Total Moles / 100 gm gas = 100/77 =1.3 moles
Let n is NO2 moles
(1.3-n ) = N2O4 moles
Mol wt of NO2 = 46
Mol wt of N2O4 = 92
n*46+ (1.3-n)*92=100
n=0.42
Therefore the given 100gm gas has following composition
NO2 = 0.42 moles or 0.42*46= 19.32 gms
N2O4=0.88 moles or 0.88*92 = 19.342 gms