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Question

The volume of water that must be added to a mixture of 250 mL of 0.6 M HCl and 750 mL of 0.2 M HCl to obtain a 0.25 M solution is:

A
200 mL
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B
250 mL
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C
400 mL
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D
300 mL
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Solution

The correct option is A 200 mL
Let the amount of water to be added is x mL.
Conserving the total moles before and after mixing:
M1V1+M2V2=MV
where M2 and V2 are the molarity and volume of 0.6 M solution.
M1 and V1 are the molarity and volume of 0.2 M solution and M and V are the molarity and volume of the final mixture.
So,
0.25×(1000+x)=(0.6×250)+(0.2×750)
On solving, x=200 mL
Therefore, amount of water added is 200 mL.

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