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The wave function ψn,l,m is a mathematical function whose value depends upon spherical polar coordinates (r,θ,ϕ) of the electron and characterized by the quantum numbers n, l and ml. Here r is distance from nucleus, θ is colatitude and ϕ is azimuth. In the mathematical functions given in the table, Z is atomic number and a0 is Bohr radius.

For hydrogen atom, the only CORRECT combination is

A
(I) (iv) (R)
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B
(I) (i) (P)
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C
(II) (i) (Q)
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D
(I) (i) (S)
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Solution

The correct option is D (I) (i) (S)
For H-atom
1s orbitalψnlm(Za0)32 e(zra0)


E4E2=13.616(13.64)=3×13.616
E6E2=13.636(13.64)=8×13.636
E4E2 is 2732 times of E6E2

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