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Question

To an evacuated vessel with movable piston under external pressure of 1 atm., 0.1 mol of He and 1.0 mol of an unknown compound (vapour pressure 0.68 atm. at 0C) are introduced. Considering the ideal gas behaviour determine the total volume (in litre) of the gases at 0C

A
7 L
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B
9 L
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C
4 L
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D
2.3L
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Solution

The correct option is A 7 L
for any ideal gas PV=nRT
0.32×V=0.1×0.082×273V=7l

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