To convert 1−butyne to 1−D−butanal, one would carry out the following steps :
(I) Sodium amide, then D2O
(II) Disiamy Iborane, then hydrogen peroxide/sodium hydroxide
(III) The transformation can not be carried out with the indicated reagents.
For conversion of 1-butyne to 1-D-butanal
CH≡C−CH2−CH3⟶CH3−CH2−CH2−CHO
so addition reaction of water with -OH groups on same carbon occurs. Here, where water is lost. Since neither of options indicate this, the indicated reagents can not be used.