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Question

Total number of moles of oxygen atoms in 3 litres O3(g) at 27C and 8.21 atm are

A
3
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B
1
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C
2
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D
none of these
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Solution

The correct option is A 3
Molar gas volume at STP = 22.4 litres

We need to convert this volume to the volume the gas would occupy at STP

p1 = 8.21 atm p2 = 1 atm
v1 = 3 litres v2 = ?
t1 = 27 + 273 = 300 k t2 = 273K
p1v1/t1 = p2v2/t2
(8.21x3)/300 = (1xv2)/273
From which
v2 = 22.4133 litres
Number of moles of O3 = 22.4133/22.4 = 1 mole
Each O3 molecule has 3 atoms of O
Number of moles of oxygen atoms = 3 x 1 = 3

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