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Question

H and S for the reaction,
Ag2O(s)2Ag(s)+12O2(g)
are 30.56kJ mol1 and 66.0J K1 respectively. Calculate the temperature at which free energy change for the reaction will be zero. Predict whether the forward reaction will be favoured above or below this temperature (in K)

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Solution

We know that,
G=HT S
At equilibrium, G=0
so that 0=HT S
or T=HS
Given that, H=30.56 kJ mol1
=30560 J mol1
S=66.0 J K1mol1
T=3056066=463K
Above this temperature, G will be negative and the process will be spontaneous in forward direction.

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