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Question

Two containers of equal volume contain the same gas at pressures P1 and P2 and absolute temperatures T1 and T2 respectively. On joining the vessels, the gas reaches a common pressure P and common temperature T. The ratio PT is equal to


A

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B

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C

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D

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Solution

The correct option is D


As the gas does not escape the number of moles of the gas is constant.

n1=P1V1RT1; n2=P2V2RT2after joiningn1+n2=P(V1+V2)RTHence, P1V1RT1+P2V2RT2=P(V1+V2)RT⇒P12T1+P22T2=PT (as V1=V2)


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