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Question

Two containers of equal volume contain the same gas at pressures P1 and P2 and absolute temperatures T1 and T2 respectively. On joining the vessels, the gas reaches a common pressure P and common temperature T. The ratio PT is equal to


A

P1T1+P2T2

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B

P1T1+P2T2(T1+T2)2

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C

P1T2+P2T1(T1+T2)2

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D

P12T1+P22T2

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Solution

The correct option is D

P12T1+P22T2


As the gas does not escape the number of moles of the gas is constant.

n1=P1V1RT1; n2=P2V2RT2after joiningn1+n2=P(V1+V2)RTHence, P1V1RT1+P2V2RT2=P(V1+V2)RTP12T1+P22T2=PT (as V1=V2)


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