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Question

Two isomeric ketones, 3-pentanone and 2-pentanone can be distinguished by:

A
I2/NaOH
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B
NaSO3H
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C
NaCN/HCl
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D
2,4-DNP
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Solution

The correct options are
A NaSO3H
D I2/NaOH
Two isomeric ketones, 3-pentanone CH3CH2COCH2CH3 and 2-pentanone CH3COCH2CH2CH3 can be distinguished by I2/NaOH. The name of the reaction is iodoform reaction and is given by compounds containing methyl keto group CH3CO
We can also use NaSO3H to distinguish 3-pentanone and 2-pentanone.

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