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Question

Two liquids A and B form type II non ideal solution which shows a minimum in its temperature-mole fraction plot (Tχ diagram). Can the two liquids be completely separated by fractional distillation?

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Solution

Two liquids A and B form type II non-ideal solution which shows a minimum in its temperature-mole fraction plot can not be completely separated by fractional distillation. Upon fractional distillation either A or B is obtained pure along with composite composition.

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