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Question

Two solutions of glucose have osmotic pressures 1.5 and 2.5atm. 1L of first is mixed with 2L of second solution, the osmotic pressure of the resultant solution is:

A
2.5+1.5atm
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B
2.51.5atm
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C
2.5+1.52atm
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D
2.16atm
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Solution

The correct option is D 2.16atm
π1=C1RT
1.5=n11×RT
n1=1.5RT
π2=C2RT
2.5=n22×RT
n2=5RT
Now, πmix=CmixRT
=(n1+n2v1+v2)RT
=1.5RT+5RT3×RT
=6.53RT×RT
πmix=2.16atm= osmostic pressure of mixture

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