C4 plants are superior to C3 plants on the following basis:
High temperature :
C4 plants can survive at high temperatures and still show an increased rate of photosynthesis while C3 plants show a decreased rate of photosynthesis at high temperatures.
Low CO2 concentration :
At low CO2 concentration, C4 plants can perform photosynthesis at a good rate while C3 plants will show photorespiration at low CO2 concentration.