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Byju's Answer
Standard XII
Chemistry
Introduction
P CH3 - CH3|C...
Question
C
H
3
−
C
H
3
|
C
H
−
C
H
3
(
P
)
B
r
2
−
−
→
h
v
X
(
m
a
j
o
r
)
L
i
A
I
H
4
−
−−−−
→
Y
(
m
a
j
o
r
)
Which of the following is true for the above reaction sequence?
A
Y and P are same compounds
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B
P is hydrogenated product of Y
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C
Y is formed by nucleophilic substitution reaction
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D
Both A and C
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Solution
The correct option is
D
Both A and C
Isobutane on bromination gives
2
-bromo-
2
-methyl propane, which on reduction with
L
i
A
l
H
4
gives back isobutane.
It is an example of nucleophilic substitution, where the attacking nucleophile is the
H
−
and the leaving group is
B
r
−
.
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0
Similar questions
Q.
Which of the following compounds will give racemic mixture of nucleophilic substitution by
O
H
−
ion?
(i)
C
H
3
−
C
H
|
C
2
H
5
−
B
r
(ii)
C
H
3
−
B
r
|
C
|
C
2
H
5
−
C
H
3
(iii)
C
H
3
−
C
H
|
C
2
H
5
−
C
H
2
B
r
Q.
Which of the following compounds will given racemic mixture on nucleophilic substitution by
O
H
⊖
ion?
(a)
C
H
3
−
C
H
|
C
2
H
5
−
B
r
(b)
C
H
3
−
B
r
|
C
|
C
2
H
5
−
C
H
3
(c)
C
H
3
−
C
H
|
C
2
H
5
−
C
H
2
B
r
Q.
What is the major product
P
in the above reaction?
C
H
3
C
H
2
−
C
H
3
|
C
|
C
H
3
−
C
|
H
O
H
−
C
H
3
H
2
S
O
4
−
−−−
→
h
e
a
t
P
M
a
j
o
r
Q.
C
H
3
−
C
H
3
|
C
|
C
H
3
−
C
H
=
C
H
2
(
i
)
H
g
(
O
A
c
)
2
,
H
2
O
−
−−−−−−−−−−
→
(
i
i
)
N
a
B
H
4
P
The product
P
of the given reaction is :
Q.
In the above reaction the attack of a nucleophile would be from which side:
3
C
H
3
−
2
C
|
H
C
H
3
−
1
C
H
2
C
l
a
q
.
K
O
H
−
−−−−
→
C
H
3
−
C
H
|
C
H
3
−
C
H
2
−
O
H
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