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Question

Upon heating KClO3 in the presence of catalytic amount of MnO2, a gas W is formed. Excess amount of W reacts with white phosphorus to give X. The reaction of X with HNO3 gives Y and Z.

Y and Z are, respectively

A
N2O3 and H3PO4
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B
N2O5 and HPO3
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C
N2O4 and HPO3
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D
N2O4 and H3PO3
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Solution

The correct option is B N2O5 and HPO3
2KClO3MnO2−−−2KCl+3O2W

P4+5O2P4O10
x

P4O10+4HNO34HPO3+2N2O5

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