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Question

Use the given bond enthalpy data to estimate the ΔH(kJ) for the following reaction.
(CH=414kJ,HCl=431kJ,ClCl=243kJ,CCl=331kJ).
CH4(g)+4Cl2(g)CCl4(g)+4HCl(g)

A
620
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B
330
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C
420
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D
105
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Solution

The correct option is D 420
The enthalpy change for the combustion reaction is the difference between the total bond enthalpy of reactants and the total bond enthalpy of products.

ΔHr=[4ΔHCH+4ΔHClCl4ΔHCCl4ΔHHCl]

Substittue values in the above expression.

ΔHr=[4×414+4×2434×3314×431]

ΔHr=420kJ

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