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Question

Using the following data, mark the option(s) where ΔH is correctly written for the given reaction.

Given that : H+(aq)+OH(aq)H2O(l);ΔH=57.3kJ
ΔHsolution of HA(g)=70.7kJ/mol
ΔHsolution of BOH(g)=20kJ/mol
ΔHionization of HA=15kJ/mol and BOH is a strong base.

A
HA(aq)+BOH(aq)BA(aq)+H2O:ΔH=42.3kJ/mol
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B
HA(g)+BOH(aq)BA(aq)+H2O:ΔH=93kJ/mol
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C
HA(g)H+(aq)+A(aq):ΔH=55.7kJ/mol
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D
B+(aq)+OH(aq)BOH(aq):ΔH=20kJ/mol
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Solution

The correct options are
A HA(aq)+BOH(aq)BA(aq)+H2O:ΔH=42.3kJ/mol
B HA(g)+BOH(aq)BA(aq)+H2O:ΔH=93kJ/mol
C HA(g)H+(aq)+A(aq):ΔH=55.7kJ/mol
HA(aq)+BOH(aq)BA(aq)+H2O:ΔH=57.3+15=42.3kJ/mol

HA(g)+BOH(aq)BA(aq)+H2O:ΔH=70.7+20+1557.3=93kJ/mol

HA(g)H+(aq)+A(aq):ΔH=70.7+15=55.7kJ/mol

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