Various products formed on oxidation of 2-5-dimethylhexan-3-one are-i CH3-CH3-CH-COOHii CH3-CH3-CH-CH2-COOHiii CH3COOHiv HCOOH

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Potassium Permanganate

Various produ...

Question

Various products formed on oxidation of 2,5-dimethylhexan-3-one are:
(i) $C H_{3} - C | C H_{3} H - C O O H$
(ii) $C H_{3} - C | C H_{3} H - C H_{2} - C O O H$
(iii) $C H_{3} C O O H$
(iv) $H C O O H$

(i) and (ii)

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(i),(ii) and (iii)

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(i), (ii), (iii) and (iv)

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(iii) and (iv)

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Solution

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C H_{3} - C O O H

C H_{2} = C H - C O O H

C_{6} H_{5} - C O O H

C_{6} H_{5} - C H_{2} - C O O H

C H_{3} - C H_{2} - C O O H

C H_{3} - C H | O H - C O O H

{C H}_{3} - C H = {C H}_{2}

{C H}_{3} - C H = C H - {C H}_{3}

{C H}_{3} - C_{3} = C H - {C H}_{3}

{C H}_{3} - {C H}_{3} | C = {C H}_{3} | C - {C H}_{3}

Which of the following compounds gives fastest reaction with HBr and why

(i) (CH3)3 COH

(ii) CH3 CH2 CH2OH

(iii) CH3 CHOH CH3

(iv) CH3 (CH3) CH CH2OH

{C H}_{3} - {N O}_{2}

{C H}_{2} - C H O

{C H}_{3} - F

{C H}_{3} - C H

C H_{3} - C H C l - C H_{2} - C H_{3}

C H_{3} - C H = C H - C H_{3}

I

I I

C H_{3} - C = ¨ N - O H

C H_{3} - C H = ¨ N - O H

I I I

I V

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