The correct option is
B Just outside the exodermis
Velamen is a spongy, multiple epidermis that covers the roots of some epiphytic or semi-epiphytic plants, such as orchid and
Clivia species. The velamen of an orchid is the white or gray covering of aerial roots. It is many cell layers thick and capable of absorbing atmospheric moisture and nutrients. Often, the roots of orchids are associated with symbiotic fungi or bacteria. The latter may fix nutrients from the air. This functionality allows the orchid to exist in locations that provide a reproductive or vegetative advantage such as improved exposure or reduced competition from other plant species. The velamen also serves a mechanical function, protecting the vascular tissues in the root cortex, shielding the root from transpirational water loss and, in many cases, adhering the plant to the substrate. Velamen is not found in breathing roots of halophytes, parasitic plants and all aerial roots. The typical orchid root has a stele of comparatively small diameter. It is surrounded by a cortex which is further enveloped by a highly specialized exodermis, most of which at maturity do not contain protoplasm. A few cells, however, are living and allow the passage of water through them. The exodermis is surrounded by velamen, consisting of one to several layers of cells, which can develop root hair under proper environmental conditions.
Thus, the correct answer is option B.