What are the drawbacks of Newland’s law of octaves?
A
Some elements were placed in same slot.
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B
His law was only applicable for elements till calcium.
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C
He did not justify the position of hydrogen.
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D
Some similar elements were placed farther apart.
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Solution
The correct option is D Some similar elements were placed farther apart. Newland's law of octaves was one among the very first model to identify a periodic pattern in the properties of elements. He found that every eighth element had properties similar to those of the first.
The drawbacks of Newland's law of octaves are -
This law was found to be applicable only till calcium. It was not applicable to elements of higher atomic masses.
The position of hydrogen along with fluorine and chlorine was not justified on the basis of chemical properties.
He placed cobalt and nickel in the same slot as that of fluorine, chlorine and bromine to fit elements in the table despite having dissimilar properties.
He placed some unlike elements under the same slot. Iron which has resemblances in its properties with cobalt and nickel has been placed far away from these elements.