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Question

What are the most probable velocity and the average velocity for a system that follows the Maxwell-Boltzmann distribution?


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Solution

Maxwell-Boltzmann distribution:

  • The Maxwell-Boltzmann distribution is frequently depicted in the graph below.
  • The y-axis of the Maxwell-Boltzmann graph represents the number of molecules per unit speed.
  • So, if the graph in a specific region is higher, it suggests there are more gas molecules traveling at those rates.
What is the Maxwell-Boltzmann distribution? (article) | Khan Academy

Most probable velocity :

  • The most likely velocity is the velocity possessed by the greatest fraction of molecules at the same temperature is most probable velocity.
  • cmp=2.R.TM
  • Here, R is the gas constant, T is the temperature, and, M is the molar mass of the gas.

Average velocity :

  • The average velocity is the displacement divided by the total time. We compute the expected value of v.
  • Caverage=8.R.Tπ.M

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