What are the products formed when diborane reacts with each of the following compounds?

B_{2} O_{3}

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H_{3} B O_{3}

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K B O_{2}

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B C l_{3}

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Solution

Reaction with $O_{2}$ :
$B_{2} H_{6} (g) + 3 O_{2} (g) \to B_{2} O_{3} (s) + 3 H_{2} O (g) + h e a t$
Reaction with $H_{2} O$ :
$B_{2} H_{6} (g) + 6 H_{2} O (l) \to 2 H_{3} B O_{3} (l) + 6 H_{2} (g)$
Reaction with $K O H$ :
$B_{2} H_{6} (g) + K O H \to 2 K B O_{2} (s) + 6 H_{2} (g)$
Reaction with $C l_{2}$ :
$B_{2} H_{6} (g) + 6 C l_{2} \to 2 B C l_{3} (g) + 6 H C l (g)$
Now we can identify the required products.

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Diborane reacts with ammonia under different condition to give a variety of products. Which of the following are formed in these conditions.

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