What are the products of heating sodium azide in the air?
N2
Na2O
Sodium azide NaN3 thermally decomposes to sodium and nitrogen around 300oC.
2NaN3→2Na+3N2
Sodium is highly reactive it readily combusts in air forming sodium oxide.
4Na+O2→2Na2O
Nitrogen does not react at such low temperatures, so NO is not formed.