When zinc electrode is joined with SHE, the Zinc electrode will act as anode (negative electrode) i.e., oxidation occurs on this electrode spontaneously.
The negative sign of standard reduction potential indicates that the electrode when joined with SHE acts as an anode and oxidation occurs on this electrode spontaneously.
Thus, E0 Zn2+/Zn=−0.76 V signifies spontaneous oxidation of Zn at anode.
Corresponding reaction at anode is:
Zn→Zn2++2e−