Coagulation is the aggregation or accumulation of colloidal particles to form a precipitate.
Coagulation is caused by the removal of colloidal particle charge.
On their surfaces, colloidal particles have the same charge.
A colloidal solution is stable due to charge.
The electrostatic force of repulsion between similarly charged particles keeps them from colliding and forming larger particles.
The repulsion between them ends when the charge is removed.
As the particles become closer, their size increases, resulting in precipitation.
Coagulation techniques:
Electrophoresis: In this method, the colloidal particles move towards the oppositely charged electrodes and get discharged and precipitated.
mixing two oppositely charged sols: In this method, equal amounts of oppositely charged particles are mixed and then they cancel out their charges and get precipitated.
Persistent dialysis: In this method, the parts of electrolytes are removed completely and the colloidal solution finally coagulates.
Addition of electrolytes: When excess amount of electrolyte is added, then the colloidal particles are precipitated.