This is a non-equilibrium condition of active medium used in laser in which number of atoms N2 in the upper energy level momentarily exceeds the number of atoms N1 in the lower energy level N1 that is, N2>>N1.
Optical pumping: Optical pumping is the process of supplying optical energy(in general in the form of short slashes of light), to the active medium with a view to transfer into the state of population inversion.