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Question

What is the action of bromine in alkaline medium on CH3CH2NO2

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Solution

Primary and secondary nitroalkanes are readily halogenated in alkaline medium. The α-hydrogens are replaced by chlorine or bromine. Primary nitroalkanes such as nitro ethane can form mono- and dihalo derivatives, whereas secondary nitroalkanes such as nitro propane can only form monohalo derivative.
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