What is the action of conc. nitric acid on, a) Zinc metal b) P4 - molecule c) S8 - molecule?
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Solution
Aluminum and zinc do not react with concentrated nitric acid since a thick, hard to dissolve oxidation layer builds (passive oxidation) that protects the metal against further assaults. Zinc, however, reacts with diluted nitric acid.
The reaction is, P4+20HNO3(conc.)→4H3PO4+20NO2+4H2O
The reaction is,S8+48HNO3(conc.)→8H2SO4+48NO2+16H2O