What is the free energy change (ΔG) when 1.0 mole of water at 100∘C and 1 atm pressure?
A
80 cal
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B
540 cal
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C
620 cal
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D
Zero
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Solution
The correct option is D Zero 1 mole of water at 100∘C and 1 atm → Steam at 100∘C and 1 atm
n = 1 T1=373K P1=1atm T2=373K P2=1atm ΔG=nRTln(P2P1) =nRTln(1)
= 0 (ln 1 = 0)