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Question

What is the ΔG for the following reaction?
Cu2+(aq)+2Ag(s)Cu(s)+2Ag+(aq)
Given:E0Cu2+/Cu=0.34V,E0Ag/Ag+=0.8V

A
-44.5 kJ
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B
44.5 kJ
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C
-89 kJ
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D
89 kJ
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Solution

The correct option is D 89 kJ
Point to remember:
Δ0G=nFE0cell
Given informations in question :
Reduction half cell
Cu2+(aq)+2eCu(s)
Oxidation half cell
Ag(s)Ag+(aq)+e
So from these half reactions we find that n=2
To calculate ΔG we need to find Eocell
Eocell = EocathodeEoanode
Eocell = EoCu2+/CuEoAg+/Ag
Eocell=0.340.8=0.46
On substituting
Δ0G=2×96500×(0.46)=8878089 kJ




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