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Introduction to Quantum Mechanical Model

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What is the molecular orbital configuration of N2 molecule and N2-ion?

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Q. Valence shell electronic configuration of ion of

N_{2}

molecule is written as

(σ 2 s)^{2} (σ^{*} 2 s)^{2} (Π 2 p)^{4} (σ 2 p)^{2} (Π^{*} 2 p)^{1}

. Hence the bond order of Nitrogen molecular ion is:-

Q. From molecular orbital theory we can give the electronic configuration of singly positive Nitrogen molecular ion

N_{2}^{+}

Q. Draw the molecular orbital diagram of

N_{2}

N_{2}^{+}

N_{2}^{-}

. Write their electronic configuration, find the bond order and predict their magnetic behaviour. Arrange the above in increasing order of bond length.

Q. From molecular orbital theory we can give the electronic configuration of singly positive Nitrogen molecular ion

N_{2}^{+}

Q. Give the Molecular Orbital Energy diagram of a)

N_{2}

O_{2}

. Calculate the respective bond order. Write the magnetic nature of

N_{2}

O_{2}

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