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Question

What is the pH of 107mol L1 HCl solution at 25C?


A

7.3

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B

6.2

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C

6.7

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D

7

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Solution

The correct option is C

6.7


For 107mol L1HCl, the concentration of H+ due to the dissociation of water will not be negligible in comparison to the concentration H+ from the acid. Hence, we have

[H+]total = [H+]acid + [H+]water

=107+107 Since[H+] in water is107 mol L1 at25C
=107(1+1)
=2×107
pH=log[H+]=log[2×107]

pH = 6.7


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