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Standard XII
Chemistry
Bond Angle
What is the r...
Question
What is the relation between bond order , and bond length, bond strength, bond dissociation energy, bond angle?
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Q.
Bond energies can be obtained by using the following relation:
Δ
H
(
r
e
a
c
t
i
o
n
)
=
∑
Bond energy of bonds, broken in the reactants
−
∑
Bond energy of bonds, formed in the products
Bond energy depends on three factors:
a.
greater is the bond length, lesser is the bond energy
b.
bond energy increases with the bond multiplicity
c.
bond energy increases with the electronegativity difference between the bonding atoms.
The heat of formation of
N
O
from its elements is
+
90
k
J
m
o
l
−
1
, What is the approximate bond dissociation energy of the bond in
N
O
?
B
E
N
≡
N
=
941
k
J
m
o
l
−
1
B
E
O
=
O
=
499
k
J
m
o
l
−
1
Q.
Bond energies can be obtained by using the following relation:
Δ
H
(reaction)
=
∑
Bond energy of bonds, broken in the reactants
−
∑
Bond energy of bonds, formed in the products
Bond energy depends on three factors:
a.
greater is the bond length, lesser is the bond energy
b.
bond energy increases with the bond multiplicity
c.
bond energy increases with the electronegativity difference between the bonding atoms.
Arrange
N
−
H
,
O
−
H
and
F
−
H
bonds in the decreasing order of bond energy:
Q.
How is the bond strength related to the bond order?
Q.
Assertion :Bond energy and bond dissociation energy have identical value for diatomic molecules Reason: Greater the bond dissociation energy, less reactive is the bond.
Q.
Bond order is associated with the strength of bond and bond length. The higher the bond order, the smaller will be the bond length and stronger will be the bond.
Arrange
O
2
,
O
+
2
,
O
−
2
and
O
2
−
2
in order of increasing bond order.
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