What should be the ratio of velocities of CH4 and O2 molecules so that they are associated with de Brogile waves of equal wave lenghs ? According to be Broglie equation = λ=hmv
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Solution
λCH4=h(mv)CH4=h16×vCH4 λO2=h(mv)O2=h32voO2 Since >CH4=>O2 ⇒h16vCH4=h32vO2⇒vCH4vO2=3216=21