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Linkage Isomerism

What type of ...

Question

What type of structural isomers are $[C o (N H_{3})_{5} B r] S O_{4}$ and $[C o (N H_{3})_{5} S O_{4}] B r$ ? Give a chemical test to distinguish the isomers?

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Solution

$[C O (N H_{3})_{5} B r] S O_{4}$ and $[C O (N H_{3})_{5} S O_{4}] B r$ are ionisation isomers.
Aqueous solution of $[C O (N H_{3})_{5} B r] S O_{4}$ will give a white ppt whit $B a C l_{2}$ solution. The ppt with $B a C l_{2}$ solution. The ppt is insoluble in conc. $H N O_{3}$ confirming presence of free $S O_{4}^{2 -}$ ion. Aqueous solution of $[C O (N H_{3})_{5} S O_{4}] B r$ will not give this test.
$[C O (N H_{3})_{5} B r] S O_{4} ⇌ [C O (N H_{3})_{5} B r]^{2 +} + S O_{4}^{2 -}$
$B a C l_{2} + S O_{4}^{2 -} \to B a S O_{4} ↓ w h i t e p p t + 2 C l^{-}$
$[C O (N H_{3})_{5} S O_{4}] B r ⇌ [C O (N H_{3})_{5} S O_{4}]^{+} + B r^{-}$
$B a C l_{2} + B r^{-} \to N o p p t$

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Similar questions

Q. (i) What type of isomers are

[C o {({N H}_{3})}_{5} B r] {S O}_{4}

[C o {({N H}_{3})}_{5} {S O}_{4}] B r

? Give a chemical test to distinguish between them.
(ii) Write the structures of optical isomers of the complex ion

{[C o {(e n)}_{2} {C l}_{2}]}^{+}

Q. What types of isomer are

[C o (N H_{3})_{5} B r] S O_{4}

[C o (N H_{3})_{5} S O_{4}] B r

[C o (N H_{3})_{5} (S O_{4})] B r

[C o (N H_{3})_{5} B r] S O_{4}

are linkage isomers.

[C o {(N H_{3})}_{5} S O_{4}] B r

[C o {(N H_{3})}_{5} B r] S O_{4}

are a pair of _______ isomers.

Q. What type of isomers are the following :

[C o (N H_{3})_{5} B r] S O_{4} a n d [C o (N H_{3})_{5} S O_{4}] B r

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