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Question

When 0.1 mol CoCl3(NH3)5 is treated with excess of AgNO3, 0.2 mole of AgCl are obtained. The conductivity of solution will correspond to

A
1:3 electrolyte
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B
1:2 electrolyte
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C
1:1 electrolyte
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D
3:1 electrolyte
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Solution

The correct option is B 1:2 electrolyte
Formation of 0.2 mole of AgCl from 0.1 mole of complex means that there are two ionizable Cl ion.

Hence, formula of the compound is [Co(NH3)5Cl]Cl2 i.e., 1:2 type electrolyte.

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