When a graph is plotted between logxm and logp, it is a straight line with an angle 45∘ and intercept 0.3010 on y−axis. If initial pressure is 0.3atm. what will be the amount of gas adsorbed per g of adsorbent:-
A
0.4
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B
0.6
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C
0.8
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D
0.1
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Solution
The correct option is B0.6 According to Freundlich adsorption isotherm, we have logxm=logk+1nlogp ∴ Slope is 1n=tan45∘⇒n=1 logk=0.3010 ⇒k=2
We know that xm=k.p1/n ⇒xm=2×(0.3)1=0.6
As we need to calculate per g of adsorbent, then x=0.6