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Question

When CuSO4 is treated with excess KCN solution, what compound(s) is/are formed?

A
K[Cu(CN)2]
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B
K3[Cu(CN)4]
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C
K2[Cu(CN)4]
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D
NCCN
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Solution

The correct option is D NCCN
(CuSO4+2KCNCu(CN)2+K2SO4)×2
2Cu(CN)2Cu2(CN)2+(CN)2
Cu2(CN)2+6KCN2K3[Cu(CN)4]
So,adding these reactions we get,
2CuSO4+10KCN2K3[Cu(CN)4]+2K2SO4+(CN)2

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