When ethyne is passed through a red hot tube, then formation of benzene takes place: ΔH∘f(C2H2)(g)=230kJmol−1 H∘f(C6H6)(g)=85kJmol−1
Calculate the standard heat of trimerisation of ethyne to benzene. 3C2H2(g)→C6H6(g)
A
205kJmol−1
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B
605kJmol−1
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C
−605kJmol−1
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D
205kJmol−1
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Solution
The correct option is C−605kJmol−1 ΔHreaction=ΔH∘f(c6H6)−3ΔH∘f(C2H2) =85−3(230) =−605kJmol−1.