When N2 goes to N+2, the N−N bond distance increase, and when O2 goes to O+2, the O−O bond distance decrease.
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Solution
When N2 goes to N+2, the N−N bond distance increase, and when O2 goes to O+2, the O−O bond distance decrease.
The bond order of the nitrogen molecule is 3. An electron from bonding pi MO is lost to form N+2. The bond order decreases to 2.5. This decreases the strength of the bond and the bond distance increase.
The bond order of oxygen is 2. An electron is lost from antibonding pi MO to form O+2. The bond order increases to 2.5. This increases the strength of the bond and the bond distance decreases.