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Question

When one gram mole of KMnO4 reacts with HCl, the volume of chlorine liberated at NTP will be :

A
11.2 litres
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B
22.4 litres
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C
44.8 litres
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D
56.0 litres
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Solution

The correct option is D 56.0 litres
Potassium permanganate reacts with hydrochloric acid according the following equation:

2KMnO4+16HCl2KCl+2MnCl2+8H2O+5Cl2

2 moles of KMnO4 produces 5 moles of Cl2

1 mole of KMnO4 will produce 2.5 moles of Cl2

Volume of 2.5 moles of Cl2=2.5×22.4=56 litres

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