When same quantity of electricity is passed through aqueous AgNO3 and H2SO4 solutions connected in series, 5.04×10−2g of H2 is liberated. What is the mass of silver (in grams) deposited? (Eq. wts. of hydrogen =1.008, silver =108)
A
54
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B
0.54
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C
5.4
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D
10.8
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Solution
The correct option is B5.4 W1=Z1ItW2=Z2ItW1W2=Z1Z2WAgWH2=ZAgZH2WAg=1081×F×1×F1.008×5.4×10−2WAg=5.4g