CameraIcon

SearchIcon

MyQuestionIcon

1

You visited us 1 times! Enjoying our articles? Unlock Full Access!

Crystal Field Split in Octahedral Complexes

When white pp...

Question

When white ppt. of $A g_{2} C O_{3}$ is dissolved in $N H_{3}$ solution, then compound X is formed.
Find the value of magnetic moment of X.

A

0

Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses

B

2

No worries! We‘ve got your back. Try BYJU‘S free classes today!

C

1

No worries! We‘ve got your back. Try BYJU‘S free classes today!

D

3

No worries! We‘ve got your back. Try BYJU‘S free classes today!

Open in App

Solution

The correct option is A 0
Reaction:
$A g_{2} C O_{3} + N H_{3} a i r ⇌ [A g (N H_{3})_{2}]^{+}$

$A g^{+} = s p$ hybridization and linear geometry
Here Ag shows +1 oxidation state.
Thus it has $d^{10}$ configuration so no unpaired d-electron and zero magnetic moments.

Suggest Corrections

thumbs-up

0

Similar questions

When white ppt. of

A g_{2} C O_{3}

is dissolved in

N H_{3}

solution, then compound

X

Predict the geometry of compound

X

.

Q. When white ppt. of

A g_{2} C O_{3}

is dissolved in

N H_{3}

solution, then compound '

X

' is formed. How many d-orbitals are involved in hybridization of '

X

Q. A yellow solid known to be a single compound is completely insoluble in hot water but dissolves in hot

d i l . H C l

to give an orange solution. When this solution is cooled, a white crystalline ppt. is formed. This white ppt. redissolves on 'heating' the solution. The compound is :

Q. (A) gives white ppt with

A g N O_{3}

N H_{3}

. (A) gives green ppt (B) with NaOH but ppt dissolves to yellow solution (C) when heated with

H_{2} O_{2}

. (C) gives yellow ppt (D) with

B a C l_{2}

.
According to above experiment complete the matrix.

Q. The aqueous solution of inorganic compound

(X)

yielded a white precipitate when treated with dilute

H N O_{3}

A g N O_{3}

. Another sample of the solution of

(X)

when treated with

N a O H

gave a white precipitate first which dissolved in excess of

N a O H

yielding a colorless solution. When

H_{2} S

gas was passed through that solution a white precipitate was obtained.

Identify the compound

(X)

and give the reactions.

View More

Join BYJU'S Learning Program

similar_icon

Related Videos

lock

Octahedral Complexes

CHEMISTRY

Watch in App

explore_more_icon

Explore more

Crystal Field Split in Octahedral Complexes

Standard XII Chemistry

Join BYJU'S Learning Program

CrossIcon