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Question

Which among the following has the lowest boiling point?

A
Aniline
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B
CH3CH2CH2NH2
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C
CH3CH2NHCH3
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D
(CH3)3N
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Solution

The correct option is D (CH3)3N
Tertiary amines (CH3)3N are not involved in intermolecular hydrogen bonding, hence their boiling point is lowest as compared to primary and secondary amines.

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