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Byju's Answer
Standard XII
Chemistry
Arrhenius Acid
Which among t...
Question
Which among the following relations is correct?
A
K
a
1
<
K
a
2
<
K
a
3
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B
K
a
1
>
K
a
2
>
K
a
3
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C
K
a
1
=
K
a
2
=
K
a
3
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D
K
a
1
>
K
a
3
>
K
a
2
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Solution
The correct option is
B
K
a
1
>
K
a
2
>
K
a
3
p
K
a
1
=
2.12
⇒
−
l
o
g
K
a
1
=
2.12
⇒
K
a
1
=
10
−
2.12
p
K
a
2
=
7.21
⇒
−
l
o
g
K
a
2
=
7.21
⇒
K
a
2
=
10
−
7.21
p
K
a
3
=
12.32
⇒
−
l
o
g
K
a
3
=
12.32
⇒
K
a
3
=
10
−
12.32
So,
K
a
1
>
K
a
2
>
K
a
3
The answer will be option
B
.
Suggest Corrections
0
Similar questions
Q.
For a polybasic acid, the dissociation constants have different value for each steps, e.g.,
H
3
A
⇌
H
+
+
H
2
A
−
;
K
=
K
a
1
H
2
A
−
⇌
H
+
+
H
A
2
−
;
K
=
K
a
2
H
A
2
−
⇌
H
+
+
A
3
−
;
K
=
K
a
3
What is the observed trend of dissociation constants in succesive stage?
Q.
What is the pH of 0.01 M glycine solution?
[For glycine,
K
a
1
=
4.5
×
10
−
3
and
K
a
2
=
1.72
×
10
−
10
at 298 K]
Q.
Which of the following is the correct option regarding
K
a
1
for the first dissociation and
K
a
2
for the second dissociation of a polyprotic acid ?
Q.
For the following three reactions a, b, and c, equilibrium constants are given:
(A)
C
O
(
g
)
+
H
2
O
(
g
)
⇋
C
O
2
(
g
)
+
H
2
(
g
)
;
K
1
(B)
C
H
4
(
g
)
+
H
2
O
(
g
)
⇋
C
O
(
g
)
+
3
H
2
(
g
)
;
K
2
(C)
C
H
4
(
g
)
+
2
H
2
O
(
g
)
⇋
C
O
2
(
g
)
+
4
H
2
(
g
)
;
K
3
Which of the following relations is correct
Q.
In the following equilibria :-
(1)
A
+
2
B
⇌
C
;
K
e
q
=
K
1
(2)
C
+
D
⇌
3
A
;
K
e
q
=
K
2
(3)
6
B
+
D
⇌
2
C
;
K
e
q
=
K
3
Hence:
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